Asymmetric Top Molecules. Part 2 by W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)

By W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)

Volume II/29 "Molecular Constants ordinarily from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy" is deliberate to seem as a sequence A, B, C and D1, D2, D3 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like within the preseding volumes II/24 and II/19, that have seemed within the years round 1999 and 1992, respectively, the diamagnetic components are prepared within the demeanour urged via Hill ("Hill's system", 1900), which means a virtually strict alphabetical order. The ionic species are incorporated within the alphabetical association of the impartial ones in every one desk. the data is grouped otherwise compared to the former volumes. All appropriate houses of a molecule and the corresponding parameters are available targeted less than its sum formulation in quantity II/29. this diminishes the necessity of turning pages simply because rotational and comparable constants, dipole moments, limitations to inner rotation, hyperfine coupling parameters, or Zeeman information have been hitherto indexed in several tables. the current subvolume II/29D2 comprises information for uneven best molecules.

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J. Chem. Phys. 47 (1967) 4137. : J. Chem. Phys. 48 (1968) 1206. : J. Chem. Phys. 52 (1970) 3222. : J. Chem. Phys. 57 (1972) 4207. : Chem. Phys. 23 (1977) 71. : J. Mol. Spectrosc. 106 (1984) 110. : J. Mol. Spectrosc. 131 (1988) 77. N: Mol. Phys. 98 (2000) 1597. : J. Mol. Spectrosc. 211 (2002) 1. : J. Chem. Phys. 121 (2004) 237. : CODATA recommended values of the fundamental physical constants: 2006, in: J. Phys. Chem. Ref. 6, 2008. 3 Internal rotation [Ref. p. 1 Hamiltonian The rotational spectrum of a molecule with internal rotation (torsion) is modified due to torsion-rotation interaction.

38) In Eq. 38), A, B, and C are the rotational constants in the PAS and Hcd the usual centrifugal distortion Hamiltonian. The main approximation made in the PAM is that the cross term –2FpP is considered as a perturbation which can be handled by successive Van Vleck transformations. 3 Internal rotation [Ref. p. 27 each torsional state vt and for each internal rotation state ı = 0 (A state), and ı = r 1 (E state) [59Her, 76Ped] as H R  F ¦ Wv(Vn ) P n   . 39) n (n) The coefficients WvV result from the Van Vleck perturbational treatment.

255914-50-2 Two isomers have been detected in the microwave spectrum, the near-parallel and the T-shaped form. Structural parameters: See [99Pee1] (nearly parallel arrangement of the monomer subunits) and [99Pee2] (T-shaped isomer). : J. Phys. Chem. A 103 (1999) 3884. : Chem. Phys. Lett. 312 (1999) 357. : J. Mol. Spectrosc. 230 (2005) 62. : 677-21-4 F CH2 F F See also: 14-307; 6-129c Structural parameters: See [97Alo]. 3073 fixed 97Alo MW CF3 torsion ν = 81(5) cm−1 Reduced Axis Method analysis, combined fit of the υτ = 0; 1; 2 torsional states.

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